Hydroboration and Organic Synthesis 9-Borabicyclo[3.3.1]nonane (9-BBN) /
9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-...
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| Format: | Electronic eBook |
| Language: | English |
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Berlin, Heidelberg :
Springer Berlin Heidelberg,
2007.
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| Online Access: | https://dx.doi.org/10.1007/978-3-540-49076-0 |
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| 020 | |a 9783540490760 |9 978-3-540-49076-0 | ||
| 024 | 7 | |a 10.1007/978-3-540-49076-0 |2 doi | |
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| 100 | 1 | |a Dhillon, Ranjit S. |e author. | |
| 245 | 1 | 0 | |a Hydroboration and Organic Synthesis |b 9-Borabicyclo[3.3.1]nonane (9-BBN) / |c by Ranjit S. Dhillon. |
| 264 | 1 | |a Berlin, Heidelberg : |b Springer Berlin Heidelberg, |c 2007. | |
| 300 | |a XIII, 586 p. |b online resource. | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 347 | |a text file |b PDF |2 rda | ||
| 505 | 0 | |a General Remarks -- Preparation and Properties -- Kinetic Studies -- Hydroboration -- Synthesis of Alcohols -- Synthesis of Aldehydes and Ketones -- Synthesis of Carboxylic Acids -- Synthesis of Esters -- Synthesis of Nitriles -- Synthesis of (E)-?,?-Unsaturated Amides -- Synthesis of Amines -- Synthesis of Halides -- Synthesis of Dialkylsulfides -- Synthesis of Thiophene Oligomers -- Synthesis of Cyclopropanes and Cyclobutanes -- Synthesis of Borinanes -- Synthesis and Transformations of Butterflyboranes: cis-Bicyclo[3.3.0]oct-1-yldialkylboranes -- Synthesis of ?-Bromoboranes -- Synthesis of Borinates -- Synthesis and Transformation of Polymers -- Synthesis of Alkali Metal 9-Boratabicyclo[3.3.1] nonane (Li, K, and Na 9-BBNH) -- Synthesis of B-R-9-BBN Not Available via Hydroboration -- Synthesis of Unsaturated Compounds -- Reduction -- Asymmetric Reduction -- Cleavage of Ethers -- trans-Metalation -- Separation of Isomers -- Diels-Alder Reaction -- Suzuki Reaction -- Miscellaneous Reactions. | |
| 520 | |a 9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-N, C-S, C-halogen, C-metal and above all C-C bonds. In addition, the suitable substituted / unsaturated R of B-R-9-BBN can be utilized to produce dienes, enynes, allenes etc. with defined stereochemistry. 9-BBN's derivatives have been elegantly used for the asymmetric reduction of ketone moiety. Diels-Alder and Suzuki reactions have expanded the utility of 9-BBN for the synthesis of a variety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations. | ||
| 650 | 0 | |a Chemistry. | |
| 650 | 0 | |a Organic chemistry. | |
| 650 | 0 | |a Medicinal chemistry. | |
| 650 | 0 | |a Biochemistry. | |
| 650 | 1 | 4 | |a Chemistry. |
| 650 | 2 | 4 | |a Organic Chemistry. |
| 650 | 2 | 4 | |a Medicinal Chemistry. |
| 650 | 2 | 4 | |a Biochemistry, general. |
| 710 | 2 | |a SpringerLink (Online service) | |
| 773 | 0 | |t Springer eBooks | |
| 776 | 0 | 8 | |i Printed edition: |z 9783540490753 |
| 856 | 4 | 0 | |u https://dx.doi.org/10.1007/978-3-540-49076-0 |
| 912 | |a ZDB-2-CMS | ||
| 950 | |a Chemistry and Materials Science (Springer-11644) | ||