Hydroboration and Organic Synthesis 9-Borabicyclo[3.3.1]nonane (9-BBN) /

9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-...

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Bibliographic Details
Main Author: Dhillon, Ranjit S. (Author)
Corporate Author: SpringerLink (Online service)
Format: eBook
Language:English
Published: Berlin, Heidelberg : Springer Berlin Heidelberg, 2007.
Subjects:
Online Access:http://dx.doi.org/10.1007/978-3-540-49076-0
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Table of Contents:
  • General Remarks
  • Preparation and Properties
  • Kinetic Studies
  • Hydroboration
  • Synthesis of Alcohols
  • Synthesis of Aldehydes and Ketones
  • Synthesis of Carboxylic Acids
  • Synthesis of Esters
  • Synthesis of Nitriles
  • Synthesis of (E)-?,?-Unsaturated Amides
  • Synthesis of Amines
  • Synthesis of Halides
  • Synthesis of Dialkylsulfides
  • Synthesis of Thiophene Oligomers
  • Synthesis of Cyclopropanes and Cyclobutanes
  • Synthesis of Borinanes
  • Synthesis and Transformations of Butterflyboranes: cis-Bicyclo[3.3.0]oct-1-yldialkylboranes
  • Synthesis of ?-Bromoboranes
  • Synthesis of Borinates
  • Synthesis and Transformation of Polymers
  • Synthesis of Alkali Metal 9-Boratabicyclo[3.3.1] nonane (Li, K, and Na 9-BBNH)
  • Synthesis of B-R-9-BBN Not Available via Hydroboration
  • Synthesis of Unsaturated Compounds
  • Reduction
  • Asymmetric Reduction
  • Cleavage of Ethers
  • trans-Metalation
  • Separation of Isomers
  • Diels-Alder Reaction
  • Suzuki Reaction
  • Miscellaneous Reactions.